ClF5 Chlorine Pentafluoride:

First draw the Lewis dot structure:
ClF5 Lewis Structure
Electron geometry: octahedral. Hybridization: sp3d2

Then draw the 3D molecular structure using VSEPR rules:


Decision:
The molecular geometry of ClF5 is square pyramidal with asymmetric charge distribution around the central atom.
Therefore this molecule is polar.

Chlorine Pentafluoride on Wikipedia.

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